oxidation state
Học thuậtThân thiện
Definition
- Noun:
- A numerical value representing the hypothetical charge of an atom if all bonds to atoms of different elements were 100% ionic: The oxidation state is a concept used in chemistry to describe the degree of oxidation (loss of electrons) of an atom within a compound. It is a useful bookkeeping tool for tracking electron transfer in redox reactions.
Usage Examples
- Noun:
- In water (H₂O), the oxidation state of hydrogen is +1 and that of oxygen is -2.
- Determining the oxidation state of carbon in organic molecules is a fundamental skill.
- The sum of the oxidation states for all atoms in a neutral molecule must equal zero.
Advanced Usage
"Assigning oxidation states": The process of determining the oxidation number based on a set of rules (e.g., the oxidation state of a pure element is 0, oxygen is usually -2, hydrogen is usually +1).
- Before balancing the redox equation, start by assigning oxidation states to each element.
"Variable oxidation state": A characteristic of some elements, especially transition metals, which can exist in multiple oxidation states.
- Iron exhibits variable oxidation states, commonly +2 and +3.
Variants and Related Words
Oxidation number (n): Often used interchangeably with "oxidation state."
- The oxidation number of sulfur in sulfate (SO₄²⁻) is +6.
Redox (adj/n): A portmanteau of reduction-oxidation, describing reactions where oxidation states change.
- Combustion is a type of redox reaction.
Synonyms
- Oxidation number: The most direct synonym.
- Oxidation degree: A less common but descriptive synonym.
Related Phrases
"Undergo a change in oxidation state": To be oxidized or reduced.
- In the reaction, the manganese ion undergoes a change in oxidation state from +7 to +2.
"Have an oxidation state of": To possess a specific oxidation number.
- Sodium in NaCl has an oxidation state of +1.
Related Concepts (Not Idioms)
- Formal charge: A related but distinct concept that assumes bonds are covalent, not ionic. It is a different electron-bookkeeping model.
- Valency: Refers to the combining power of an element, often related to but not the same as oxidation state.
Noun
- the degree of oxidation of an atom or ion or molecule; for simple atoms or ions the oxidation number is equal to the ionic charge
- the oxidation number of hydrogen is +1 and of oxygen is -2